SELECT b.BatchID,
x.XmlCol.value('(ReportHeader/OrganizationReportReferenceIdentifier)[1]','VARCHAR(100)') AS OrganizationReportReferenceIdentifier,
x.XmlCol.value('(ReportHeader/OrganizationNumber)[1]','VARCHAR(100)') AS OrganizationNumber
FROM Batches b
CROSS APPLY b.RawXml.nodes('/CasinoDisbursementReportXmlFile/CasinoDisbursementReport') x(XmlCol);
डेमो:SQLFiddle